Chlorotrifluoride. ), perchloryl fluoride (! Things I Won't Work With: Dioxygen Difluoride. First discovered back in the 1930s, chlorine trifluoride is a rather curious chemical that easily reacts, sometimes explosively, with just about every known substance on Earth. I found out about chlorine trifluoride from a blog article by Derek Lowe, category “Stuff I won’t work with”, title “Sand won’t save you now”. Chlorine fluoride (ClF3) Trifluorure de chlore. If it's the first time you've seen it, I recommend going through the whole "Things I Won't Work With" archives[0]. . ), tetrafluorohydrazine (how on Earth. Chemist Derek Lowe's "Things I Won't Work With" series is a masterpiece of scientific horror, and how I first learned about chlorine trifluoride. ), perchloryl fluoride (! . One more from same series. It reacts with water to form chlorine and hydrofluoric acid with release of … They're a great read. 7790-91-2. TIL that the chemical chlorine trifluoride, is so flammable it can set virtually anything on fire. Chlorine trifluoride, ClF3, or “CTF” as the engineers insist on calling it, is a colorless gas, a greenish liquid, or a white solid. Reminds me of Chlorine Trifluoride, which has been described as follows: "It is, of course, extremely toxic, but that's the least of the problem. His blog has a section called "Things I Won't Work With" and it is hilarious. As in: sand will put out certain fires that water won’t — but it doesn’t help here because CTF eats right through sand, rock, and concrete. meanduck on Mar 14, 2016. Reminds me of the discussion around chlorine trifluoride: Things I Won't Work With posted: It is hypergolic with every known fuel, and so rapidly hypergolic that no ignition delay has ever been measured. ), and on, and on. It boils at 12° (so that a trivial pressure will keep it liquid at room temperature) and freezes at a convenient —76°. ... water ice (explosion, natch), chlorine ("violent explosion", so he added it more slowly the second time), red phosphorus (not good), bromine fluoride, chlorine trifluoride (say what? Posted by Derek ... chlorine trifluoride (say what? . In the 1950's, a 1 TON spill of this chemical burned through a foot of concrete, another 3 feet of sand and gravel beneath that, with a side of deadly clouds of corrosive hydrofluoric acid gas. Of all of the materials that I, as a chemist, do NOT want to meet, this material has got to be right close to the top of the list. Chlorine trifluoride appears as a colorless gas or green liquid with a pungent odor. Yup. ), tetrafluorohydrazine (how on Earth. Molecular Weight: 92.45 g/mol. Chlorine trifluoride is one of those truly nasty chemicals that I have not and would not deal with. Yes, chlorine trifluoride will set asbestos on fire. Just to get the ball rolling, here’s a few of the more unusual things chlorine trifluoride is known to set fire to on contact: glass, sand, asbestos, rust, concrete, people, pyrex, cloth, and the dreams of children The reaction here also doesn’t require atmospheric oxygen to burn, so trying to use that method of fire suppression won’t work either. CHLORINE TRIFLUORIDE. Boils at 53°F. .
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